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Plant Diversity ›› 1992, Vol. 14 ›› Issue (03): 1-3.

• 研究论文 •    

云南昭通产苦丁茶的配糖体成分

贺震旦 刘玉青 杨崇仁   

  1. 中国科学院昆明植物研究所植物化学开放研究实验室
  • 出版日期:1992-06-25 发布日期:1992-06-25

GLYCOSIDES FROM LIGUSTRUM PURPURASCENS

HE Zheng-Dan, LIU Yu-Qing, YANG Chong-Ren   

  1. Laboratory of Phytochemistry,Kunming Institute of Botany,The Chinese Academy of Science,Kunming 650204
  • Online:1992-06-25 Published:1992-06-25

摘要: 苦了茶是我国南方各民族常饮用的一类茶。云南昭通地区的苦丁茶以木樨科植物紫茎女贞(Ligustrum purpurascens Y.C.Yang)为原料。从该植物的叶中分离到2个新的苯丙素类配糖体成分,命名为紫茎女贞甙(ligupurpuroside)A和B,同时还分离到阿克甙、桂花叶甙B的顺反异构体混合物、以及2-(3,4-羟基苯)乙基(3—O-α-L-鼠李吡喃糖基)(4-O-对香豆酰基)-O-β-D-葡萄吡喃糖甙的顺反异构体混合物。同时还分离到3个已知黄酮甙:木樨草素-7-葡萄糖甙,大波斯菊甙和野漆树甙。

关键词: 木樨科, 紫茎女贞, 苯丙素类配糖体, 紫茎女贞甙

Abstract: Ku-Ding-Cha as a famous traditional drinking tea was used in the south China for a long time. There are a lot of plants which belong to different families and genera were used as its original ma-terials. From the leaves of Ligustrwn purpurascens Y. C. Yang (Oleaceae), a kind of the materials of Ku-Ding-Cha in Yunnan Province, two new phenylpropanoid glycosides, ligupurpuroside A and B were isolated, together with the Z / E isomer mixture of 2- (3, 4-hydroxyphenyl) ethyl (3- 0- α- L-rhamnopyranosyi) ( 4- 0- coumaroyD-0-β-D-glucopyranoside, the mixture of osmanthuside B and its cis isomer, as well as acteoside and three known flavonoid glycosides, luteolin -7-glucoside, cosmosiin and rhoifolin. On the basis of spectroscopic evidence, the structures of the new glycosides were established as 2-(3,4-dihydroxyphenyl) ethyl- [3- 0-α- L-rhamno-pyranosyi (1→ 4)-α-L-rhamnopyranosyl] [ 4-0 -E-caffeoyl] -0-β-D-glucopyranoside and 2-β-hydroxyphenyl) ethyl [3-0 -α-L-rhamnopyranosyl(l →4)-α-L-rhamnopyranosyl) C 4-0-E-p-couOTaroyl) -0 -β-D-glucopyranoside, respectively.

Key words: Oleaceaei Ligustrum purpurascens